Answer:
Na2S2O3 + AgBr → NaBr + Na3[Ag(S2O3)2]
Step-by-step explanation:
First check that the given equation is balanced ... it isn't ... so the first thing to do is balance the equation:
balancing Na:
2Na2S2O3 + AgBr → NaBr + Na3[Ag(S2O3)2]
and everything is now balanced so we've got the balanced equation
molar mass AgBr = 107.87 + 79.90 = 187.77 g/mol
mol AgBr available = 42.7 g AgBr x [1 mol / 187.77 g] = 0.2274 mol AgBr
from the balanced equation the mole ratio AgBr : Na2S2O3 = 1 : 2
so mol Na2S2O3 required = 0.2274 mol AgBr x [ 2 mol Na2S2O3 / mol AgBr]
= 0.455 mol Na2S2O3 (to 3 sig figs)