Question

For Na2HPO4:(( (Note that for H3PO4, ka1= 6.9x10-3, ka2 = 6.4x10-8, ka3 = 4.8x10-13 ) a) The active anion is H2PO4- b) The active anion is HPO4 3- c) is basic d) Is acidic

Answer 1

Check the explanation

Step-by-step explanation:

Answer – Given,
`H_3PO_4` acid and there are three Ka values

`K_(a1)=6.9x10^8, K_(a2) = 6.2X10^8, and K_(a3)=4.8X10^(13)`

The transformation of
`H_2PO_4- (aq) to HPO_4^2-(aq)`is the second dissociation, so we need to use the Ka2 = 6.2x10-8 in the Henderson-Hasselbalch equation.

Mass of KH2PO4 = 22.0 g , mass of Na2HPO4 = 32.0 g , volume = 1.00 L

First we need to calculate moles of each

Moles of KH2PO4 = 22.0 g / 136.08 g.mol-1

= 0.162 moles

Moles of Na2HPO4 = 32.0 g /141.96 g.mol-1

= 0.225 moles

[H2PO4-] = 0.162 moles / 1.00 L = 0.162 M

[HPO42-] = 0.225 moles / 1.00 L = 0.225 M

Now we need to calculate the pKa2

pKa2 = -log Ka

= -log 6.2x10-8

= 7.21

We know Henderson-Hasselbalch equation

pH = pKa + log [conjugate base] / [acid]

pH = 7.21 + log 0.225 / 0.162

= 7.35

The pH of a buffer solution obtained by dissolving 22.0 g of KH2PO4 and 32.0 g of Na2HPO4 in water and then diluting to 1.00 L is 7.35