Final answer:
After the reaction between HBr and NaCN in the buffer solution, the species present will include HCN, excess HBr, NaBr, and any unreacted HCN from the original buffer.
Step-by-step explanation:
The student has added a 0.25 mol sample of HBr to a buffer solution containing 0.68 M HCN and 0.35 M NaCN. After this addition, the species that will exist in the solution are the result of the reaction between HBr and the NaCN, because HBr is a strong acid and will react with the base component of the buffer (NaCN) first before affecting the pH significantly.
The reaction can be represented by the following equation:
HBr + NaCN → NaBr + HCN
Since there is less moles of NaCN than HBr, the NaCN is the limiting reactant and will be completely consumed. The resulting species in the final solution will, therefore, include HCN, excess HBr, the newly formed NaBr, and any unreacted HCN from the original buffer.