Answer : The partial pressure of both oxygen and nitrogen is, 61.8 atm and 117.8 atm respectively.
Explanation :
First we have to calculate the moles of
and
![N_2](https://img.qammunity.org/2021/formulas/chemistry/college/sc9tv8o98s5gjg6a7rp36clc4na79mnyfw.png)
![\text{Moles of }O_2=\frac{\text{Given mass }O_2}{\text{Molar mass }O_2}=(5.00g)/(32g/mol)=0.156mol](https://img.qammunity.org/2021/formulas/chemistry/high-school/6bk70n32l2390et1tg1rzn8gspkihxjw9r.png)
and,
![\text{Moles of }N_2=\frac{\text{Given mass }N_2}{\text{Molar mass }N_2}=(8.31g)/(28g/mol)=0.297mol](https://img.qammunity.org/2021/formulas/chemistry/high-school/512n4j5ykq0aind3zuqmjkbh5a4ifrlx97.png)
Now we have to calculate the mole fraction of
and
![N_2](https://img.qammunity.org/2021/formulas/chemistry/college/sc9tv8o98s5gjg6a7rp36clc4na79mnyfw.png)
![\text{Mole fraction of }O_2=\frac{\text{Moles of }O_2}{\text{Moles of }O_2+\text{Moles of }N_2}](https://img.qammunity.org/2021/formulas/chemistry/high-school/ra25kf7wmw3l6bmzprh0c2ew6qgl0snraz.png)
![\text{Mole fraction of }O_2=(0.156)/(0.156+0.297)=0.344](https://img.qammunity.org/2021/formulas/chemistry/high-school/s2n5f0cyx2u0qtxi1nluqkzoxc4vq3bevb.png)
and,
![\text{Mole fraction of }N_2=\frac{\text{Moles of }N_2}{\text{Moles of }O_2+\text{Moles of }N_2}](https://img.qammunity.org/2021/formulas/chemistry/high-school/5ztuovbq47qugzkq7lpks72dpwi4ikw6dq.png)
![\text{Mole fraction of }O_2=(0.297)/(0.156+0.297)=0.656](https://img.qammunity.org/2021/formulas/chemistry/high-school/dy0gfkmn5nq2uh5787pjp18g4ahmxniyci.png)
Now we have to calculate the partial pressure of both oxygen and nitrogen.
According to the Raoult's law,
![p_i=X_i* p_T](https://img.qammunity.org/2021/formulas/chemistry/high-school/ii6ohavs4f1pgzu893eviry25tz2v85gpl.png)
where,
= partial pressure of gas
= total pressure of gas = 179.6 atm
= mole fraction of gas
![p_(O_2)=X_(O_2)* p_T](https://img.qammunity.org/2021/formulas/chemistry/high-school/ouymv1s4ljkhe1sv8jdqwvnaw2nija9dff.png)
![p_(O_2)=0.344* 179.6atm=61.8atm](https://img.qammunity.org/2021/formulas/chemistry/high-school/yxww54ov4lyifzj7g167fqk48vh3kn3pu2.png)
and,
![p_(N_2)=X_(N_2)* p_T](https://img.qammunity.org/2021/formulas/chemistry/high-school/r57uwecgsjm5ovvqp52woq7nbaqv66dil9.png)
![p_(N_2)=0.656* 179.6atm=117.8atm](https://img.qammunity.org/2021/formulas/chemistry/high-school/yag2c460ledcsptvueewqv5k1f8amt0jo3.png)
Thus, the partial pressure of both oxygen and nitrogen is, 61.8 atm and 117.8 atm respectively.