Final answer:
The molarity of the HCl solution is found to be 0.830 M by using the titration method with a 0.145 M NaOH solution to neutralize 5.00 mL of HCl.
Step-by-step explanation:
The question deals with the calculation of the molarity of an HCl solution using the technique of titration with a known concentration of NaOH. In this titration, the balanced chemical reaction is:
HCl + NaOH → NaCl + H2O
Given that 28.6 mL (or 0.0286 L) of 0.145 M NaOH solution is required to neutralize 5.00 mL of HCl solution, we can calculate the number of moles of NaOH reacted:
Moles of NaOH = Volume (L) × Molarity (M) = 0.0286 L × 0.145 M = 0.004149 mol NaOH
Since the molar ratio of HCl to NaOH is 1:1, the moles of HCl will also be 0.004149. To find the molarity of the HCl solution, we use the formula:
Molarity of HCl = Moles of HCl / Volume of HCl (L) = 0.004149 mol / 0.005 L = 0.830 M
Therefore, the molarity of the HCl solution is 0.830 M, rounded to three decimal places.