Answer:
Pb: 22.4 at%
Sn: 77.6 at%
Step-by-step explanation:
It is possible to find at% of Pb and Sn converting mass in moles using molar mass assuming a basis of 100g, thus:
Pb: 33.5g × (1mol / 207.2g) = 0.1617mol
Sn: 66.5g × (1mol / 118.7g) = 0.5602mol
Total moles: 0.1617mol + 0.5602mol = 0.7219mol
Composition in at%:
Pb: 0.1617mol / 0.7219mol × 100 = 22.4 at%
Sn: 0.5602mol / 0.7219mol × 100 = 77.6 at%
I hope it helps!