160k views
0 votes
Identify the following compound from its IR and proton NMR spectra. C5H6O: IR: 3300 (sharp), 2102, 1634 cm–1 NMR: δ 3.10 (1H, d, J = 2 Hz); δ 3.79 (3H, s); δ 4.52 (1H, doublet of doublets, J = 6 Hz and 2 Hz); δ 6.38 (1H, d, J = 6 Hz)

User Tfl
by
5.9k points

2 Answers

2 votes

Final answer:

The compound C5H6O is likely to be 3-methyl-1-pentyne, characterized by IR absorption peaks at 3300 cm−1 (alkyne C≃H stretch) and 2102 cm−1 (C≃C triple bond). The NMR spectrum suggests a methyl group, and hydrogens adjacent to both a double bond and a triple bond.

Step-by-step explanation:

To identify the compound from its IR and proton NMR spectra, let's examine the given peaks. The IR spectrum shows sharp absorption at 3300 cm−1, which is indicative of a terminal alkyne group C≃H. This is further confirmed by the characteristic alkyne absorption at 2102 cm−1. The peak at 1634 cm−1 suggests a carbon-carbon double bond.

Turning to the NMR spectrum, the signal at δ 3.10 (1H, d, J = 2 Hz) may correspond to the hydrogen on a carbon adjacent to a triple bond due to the small coupling constant. The singlet at δ 3.79 (3H, s) is likely a methyl group, suggesting an O-CH3 group because it is not split by any adjacent hydrogens.

The doublet of doublets at δ 4.52 (1H, J = 6 Hz and 2 Hz) alongside the δ 6.38 (1H, d, J = 6 Hz) suggest these hydrogens are coupled to each other and one is adjacent to a double bond while the other is adjacent to a triple bond.

From these spectroscopic features, the compound is likely to be 3-methyl-1-pentyne. Its structure includes a terminal alkyne and a double bond, consistent with the observed IR absorptions, and the NMR peaks correspond to the unique hydrogens in this molecule.

User Pinks
by
6.9k points
2 votes

Answer:

trans-1-metoxy-1-buten-3-yne

Formula:HC_CCH=CHOCH3

structural diagram is attached

Step-by-step explanation:

1-METHOXY-1-BUTEN-3-YNE, MIXTURE OF CIS- & TRANS-ISOMERS 98%

CAS No.3685-19-6

Chemical Name:1-METHOXY-1-BUTEN-3-YNE, MIXTURE OF CIS- & TRANS-ISOMERS 98%

CBNumber:CB91499271

Molecular Formula:HC_CCH=CHOCH3

Formula Weight:0

MOL File:Mol file

Identify the following compound from its IR and proton NMR spectra. C5H6O: IR: 3300 (sharp-example-1
User Jhnclvr
by
6.7k points