Final answer:
To find the concentration of Ca(OH)2 with a pH of 12.11, calculate the pOH, determine [OH-], and then halve it because Ca(OH)2 disassociates into two OH- ions. The concentration of Ca(OH)2 is 0.0065 M.
Step-by-step explanation:
To calculate the concentration of an aqueous solution of Ca(OH)2 with a pH of 12.11, we first need to calculate the pOH, which is the negative logarithm of the hydroxide ion concentration ([OH−]). Since pH + pOH = 14, we get:
pOH = 14 - pH = 14 - 12.11 = 1.89
Now we use the hydroxide ion concentration formula:
[OH−] = 10−pOH = 10−1.89 ≈ 1.29 x 10−2 M
Ca(OH)2 dissociates into one Ca2+ ion and two OH− ions. Therefore, the concentration of Ca(OH)2 is half the concentration of [OH−]:
[Ca(OH)2] = [OH−] / 2 = (1.29 x 10−2 M) / 2 ≈ 6.45 x 10−3 M
Thus, the concentration of Ca(OH)2 is 0.0065 M, rounded to two significant figures.