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g Calculate the activation energy (considering the Arrhenius expression) for a process that proceeds at 9x10-14 mol/sec at a temperature of 600K and at a rate of 6x10-11 mol/sec at 850K.

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Answer: Activation energy


E_(a)=110.243 kJ/mol

Step-by-step explanation:

Arrhenius expression activation energy is given by


k=Ae^{(-E_(a))/(RT)

where
k is the rate constant,
A is the pre-exponential factor


R=The gas constant is 8.314 J / mol·K and
T is temperature

By substituting the values in the above equation we get two equations


k_(1)=Ae^{(-E_(a))/(RT_(1))}\\9* 10^(-14)=Ae^{(-E_(a))/(8.314* 600)}...................(1)\\k_(2)=Ae^{(-E_(a))/(RT_(2))}\\6* 10^(-11)=Ae^{(-E_(a))/(8.314* 850)}...................(2)

by solving 1 and 2, we get


1.5* 10^(-3)=\frac{e^{(-E_(a))/(8.314* 600)}}{e^{(-E_(a))/(8.314* 850)}}\\1.5* 10^(-3)\tiimes {e^{(-E_(a))/(8.314* 850)}={e^{(-E_(a))/(8.314* 600)}\\ln(1.5* 10^(-3))\tiimes+ln( {e^{(-E_(a))/(8.314* 850)})=ln({e^{(-E_(a))/(8.314* 600)})\\-6.50+ -E_(a)/(8.314* 850)={(-E_(a))/(8.314* 600)\\E_(a)=110.243 kJ/mol

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