Answer : The mass of the Al piece that added was, 6.52 grams.
Explanation :
In this problem we assumed that heat given by the hot body is equal to the heat taken by the cold body.


where,
= specific heat of Al =

= specific heat of water =

= mass of Al = ?
= mass of water = 49.0 g
= final temperature of mixture =

= initial temperature of Al =

= initial temperature of water =

Now put all the given values in the above formula, we get


Therefore, the mass of the Al piece that added was, 6.52 grams.