Answer : The mass of the Al piece that added was, 6.52 grams.
Explanation :
In this problem we assumed that heat given by the hot body is equal to the heat taken by the cold body.
![q_1=-q_2](https://img.qammunity.org/2021/formulas/chemistry/college/ci1uvgegxwl3f5rpx3vscvsacjaiwja6yb.png)
![m_1* c_1* (T_f-T_1)=-m_2* c_2* (T_f-T_2)](https://img.qammunity.org/2021/formulas/chemistry/college/qyvqmycd0c0tziyigjg5lblqrbm4j5bbis.png)
where,
= specific heat of Al =
![0.902J/g^oC](https://img.qammunity.org/2021/formulas/chemistry/college/qcpe2ixpn2tmn27hg0kzef7bm9vuos80b8.png)
= specific heat of water =
![4.184J/g^oC](https://img.qammunity.org/2021/formulas/chemistry/college/vuq03mq1j2jefju0h90z30l4lgawynvg8d.png)
= mass of Al = ?
= mass of water = 49.0 g
= final temperature of mixture =
![24.1^oC](https://img.qammunity.org/2021/formulas/chemistry/college/tph3ivd5301vf193g7nzrrlrym9uk9uv8r.png)
= initial temperature of Al =
![97.3^oC](https://img.qammunity.org/2021/formulas/chemistry/college/lxsg0s7u7um5vnsslkdrtchtd8pze46dtc.png)
= initial temperature of water =
![22.0^oC](https://img.qammunity.org/2021/formulas/chemistry/college/7m2swr4g1hudidpp976617wadrmmnshbhx.png)
Now put all the given values in the above formula, we get
![m_1* 0.902J/g^oC* (24.1-97.3)^oC=-49.0g* 4.184J/g^oC* (24.1-22.0)^oC](https://img.qammunity.org/2021/formulas/chemistry/college/3mict1vh91ld7iy6z4pogaa63hte54e2xp.png)
![m_1=6.52g](https://img.qammunity.org/2021/formulas/chemistry/college/nzje8jy3yflmjgwfcdkl9mta0ehv9y8goc.png)
Therefore, the mass of the Al piece that added was, 6.52 grams.