I suppose that you want to produce a 0.25 M solution of KCl
You do not want tp produce 0.25 mol of KCl.
Molar mass KCl = 39.1 + 35.45 = 74.55 g/mol
Mass of 0.25 mol KCl = 0.25 mol * 74.55 g/mol =18.64 g
To produce a 0.25 M solution of KCl = 18.64 g would require a solution volume of 1.0 L or 1000 mL
You have only 5.00 g ( NOT 5.00 gm) of KCl
Volume of solution required = 5 g / 18.64 g * 1000 mL = 268 mL solution
You dissolve the 5 g KCl in some water and then make up the final solution volume to 268 mL
This does NOT mean that you dissolve the 5 g KCl in 268 mL water .