3CH4 refers to three molecules of a
compound and C3H12 refers to only one
molecule of a compound.
3CH4 and C3H12 are actually different
molecules though they contain the same
number and types of atoms. Recall that both
of them are hydrocarbons hence they
contain only hydrogen and carbon.
3CH4 refers to three molecules of methane
while C3H12 refers to one molecule of
diphenyl methane. Hence 3CH4 refers to
three molecules of a compound and C3H12
refers to only one molecule of a compound.