Hi there!
An example of this could be when a ball is thrown vertically into the air and reaches the TOP of its trajectory.
When an object is thrown with a vertical velocity, the acceleration due to gravity results in a decrease in its positive (upward) velocity until it reaches its highest point, where the instantaneous velocity = 0 m/s and the object begins to fall back down (negative velocity).
Additionally, throughout its entire trajectory, the ball experiences an acceleration due to gravity of g = 9.8 m/s², even at its highest point where there is a velocity = 0 m/s.