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Why is better separation of two liquids achieved by slow rather than fast distillation?.

User GorillaMoe
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Answer:

A one mL per minute rate (or slower) is recommended for best results in a fractional distillation; simple can go faster. Slow, gradual distillation essentially allows the best equilibration and heat transfer. If you heat too fast, vapors may not condense as quickly as desired, and may waste some of the column.

User Bill Garrison
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