73.5k views
2 votes
SiO2 has a melting point of 1700°C, whereas CO2 has a melting point of -78°C. What is the reason for this huge difference between two elements in the same group?​

1 Answer

6 votes

Final answer:

The melting point of SiO2 is higher than that of CO2 because SiO2 is a covalent network solid with a strong three-dimensional bond network, whereas CO2 consists of individual molecules held together by weak intermolecular forces.

Step-by-step explanation:

The huge difference in melting points between silicon dioxide (SiO2) and carbon dioxide (CO2) is due to their different structures and bonding. Silicon dioxide is a covalent network solid where each silicon atom is bonded to four oxygen atoms in a tetrahedral structure, creating a strong, three-dimensional, continuous network. This results in a much higher melting point of 1700°C since breaking the continuous network requires a significant amount of energy.

In contrast, carbon dioxide consists of individual CO2 molecules held together by very weak intermolecular forces, making it much more volatile and having a low melting point of -78°C. Here, the molecules have strong double bonds within, but between the molecules, the forces are weak, thus requiring much less energy to overcome these forces and melt the solid.

User Remykarem
by
4.6k points