An obvious substitution would be to take u = x - y and v = x + 2y, so that 0 < u < 1 (which follows from y = x ==> x - y = 0 and y = x - 1 ==> x - y = 1), and 0 < v < 1.
Solve for x and y in terms of u and v :
u - v = (x - y) - (x + 2y) = -3y ==> y = (v - u)/3
2u + v = 2 (x - y) + (x + 2y) = 3x ==> x = (2u + v)/3
Compute the Jacobian and its determinant:

Now in the integral, we have
