Answer: The equations in column A is matched with gas laws in column B as follows:
21. PV = nRT : (g) Ideal gas law
22.
: (f) Avogadro's law
23.
: (e) Combined Gas Law
24.
: (d) Gay-Lusaac's law
25.
: (c) Charles' law
26.
: (b) Boyle's law
27.
: (a) Graham's Law of effusion
Step-by-step explanation:
(A) Ideal gas law: It states that the product of pressure and volume is directly proportional to the product of number of moles and temperature.
So, PV = nRT
where,
P = pressure
V = volume
n = no. of moles
R = gas constant
T = temperature
- Boyle's law: At constant temperature, the pressure of a gas is inversely proportional to volume.
So,
![P_(1)V_(1) = P_(2)V_(2)](https://img.qammunity.org/2022/formulas/physics/high-school/nd9517xymag6p9dd9z7omrpxrtijikxfwg.png)
- Charles' law: At constant pressure, the volume of a gas is directly proportional to temperature. So,
![V \propto T\\(V_(1))/(T_(1)) = (V_(2))/(T_(2))\\V_(1)T_(2) = V_(2)T_(1)](https://img.qammunity.org/2022/formulas/physics/high-school/wdskdzu30snadc081h3bwi1dej62kcpgb6.png)
- Gay-Lussac's law: At constant volume, the pressure of a gas is directly proportional to temperature.
So,
![P_(1)T_(2) = P_(2)T_(1)](https://img.qammunity.org/2022/formulas/physics/high-school/di33zymmuw1biqpao2rs7vudyqr2hbxyj0.png)
- Avogadro's law: At same temperature and pressure, the volume of gas is directly proportional to moles of gas.
So,
![V_(1)n_(2) = V_(2)n_(1)](https://img.qammunity.org/2022/formulas/physics/high-school/2fz83mn4sdzbui3wwde3kospsjeohheymj.png)
- Combined gas law: When Boyle's law, Charles' law, and Gay-lussac's law are combined together then it is called combined gas law. So,
![(P_(1)V_(1))/(T_(1)) = (P_(2)V_(2))/(T_(2))\\or, P_(1)V_(1)T_(2) = P_(2)V_(2)T_(1)](https://img.qammunity.org/2022/formulas/physics/high-school/kl1uvhjkbpca64uddmigboxj0pl20c0ca8.png)
- Graham's law of effusion: It states that the rate of effusion of a gas is inversely proportional to the square root of mass of its particles.
![(v_(1))/(v_(2)) = \frac{\sqrt{MM_(1)}}{MM_(2)} = \frac{\sqrt{p_(1)}}{p_(2)}](https://img.qammunity.org/2022/formulas/physics/high-school/tb4qa8gm1bf3ln1uxaqzr9m532a11nypzf.png)
Thus, we can conclude that equation in column A is matched with gas laws in column B as follows:
21. PV = nRT : (g) Ideal gas law
22.
: (f) Avogadro's law
23.
: (e) Combined Gas Law
24.
: (d) Gay-Lusaac's law
25.
: (c) Charles' law
26.
: (b) Boyle's law
27.
: (a) Graham's Law of effusion