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During the electrolysis of Molten LiBr : Li is reduced and Br are oxidized .
Lithium Metal is produced at the Cathod during the electrolysis of Molten LiBR .
In the aquous LiBr : In aquous LiBr potential of Li is greater than the of water then Li is reduced to produce solid Li ion. As well As aqueous LiF ( electrolysis)and Molten LiF electrolysis produce the gas.
aqueous LiF: Oxygen gas.
Molten LiF : Flourine gas.