Hi there!
A function is a set of ordered pairs that do not have same x-values.
In a set of ordered pairs, If two or more ordered pairs have same x-values, they are not considered as a function but rather a relation instead.
From the question above, you notice that two of the choices have same x-values and others don't have.
The relations that are not functions are the second choice and fourth choice because two ordered pairs have same x-values.
Any questions can be asked through comment.
Furthermore, a function is also a relation but a relation isn't always a function.
Hope this helps, and Happy Learning! :)