c = 22.3 km
Explanation:
You can solve this problem using cosine law:

where a and b are the legs of the triangle, c is the unknown length and the angle gamma is the angle opposite length c. We know that
a = 50 km
b= 52.4 km
gamma = 25°
c^2 = (50 km)^2 + (52.4 km)^2 -2(50)(52.4)cos25°
= 496.707 km^2
or
c = 22.3 km