To answer your question, the "72 degrees Fahrenheit=room temperature" is considered from internal body temperatures being 98.6 degrees +/-, thus making the temperature of skin to be around 72-76 degrees Fahrenheit. That is why a temperature around that range is usually comfortable and coined as room temperature.
Hot:84-99 F (29-37.5 C) Warm:70-84 F (21-29 C) Cool:55-69 F (13-21 C) Cold: Below 55 F (Below 13 C)
Answer:
(Which means 72 is warmer)