231k views
2 votes
If 164.8 g of iodine monobromide is combined with 62.4 g of ammonia, determine the amount of excess reactant that remains after the reaction is completed and the percentage yield of nitrogen triiodide if 96.4 is produced?

1 Answer

1 vote

Answer:


m_(NH_3)^(leftover)=57.88g


Y= 92.0\%

Step-by-step explanation:

Hello there!

In this case, according to the following chemical reaction between iodine monobromide and ammonia:


3IBr+NH_3\rightarrow NI_3+3HBr

It turns out firstly necessary to identify the limiting reactant, by considering the proper molar masses and the 3:1 and 1:1 mole ratios of iodine monobromide to nitrogen triiodide and ammonia to nitrogen triiodide respectively:


n_(NI_3)^(by\ IBr)=164.8gIBr*(1molIBr)/(206.81gIBr)*(1molNI_3)/(3molIBr) =0.266molNI_3\\\\n_(NI_3)^(by\ NH_3)=62.4gNH_3*(1molNH_3)/(17.03gNH_3)*(1molNI_3)/(1molNH_3) =3.66molNI_3

Thus, we conclude that the limiting reactant is IBr as is yields the fewest moles of nitrogen triiodide product. Next, we can calculate the reacted grams of ammonia as the excess reactant:


m_(NH_3)^(reacted)=0.266molNI_3*(1molNH_3)/(1molNI_3)*(17.03gNH_3)/(1molNH_3)=4.52gNH_3

And therefore the leftover of ammonia is:


m_(NH_3)^(leftover)=62.4g-4.52g=57.88g

Next, the percent yield is calculated by firstly calculating the theoretical yield of nitrogen triiodide as follows:


m_(NI_3)^(theoretical)=0.266molNI_3*(394.72gNI_3)/(1molNI_3) =104.8gNI_3

And finally the percent yield by dividing the given actual yield of 96.4 g by the previously computed theoretical yield:


Y=(96.4g)/(104.8g)*100\%\\\\Y= 92.0\%

Best regards!

User Adam McKee
by
4.3k points