Final answer:
The measure of angle BCA is 90 degrees because a tangent to a circle is perpendicular to the radius at the point of tangency, forming a right triangle.
Step-by-step explanation:
The measure of angle BCA in the context provided where line BC is tangent to a circle centered at A is 90 degrees. When a line is tangent to a circle, it is perpendicular to the radius drawn to the point of tangency. Consequently, since line BC is tangent to the circle at point B, and assuming that the radius from the center A to the point B is also line AB, triangle ABC would be a right triangle with angle BCA as the right angle.