To find the next time when Bus A and Bus B leave the station at the same time, we need to find the first common multiple of the time intervals of the two buses.
The time intervals for Bus A are 75, 150, 225, 300, and so on.
The time intervals for Bus B are 15, 30, 45, 60, 75, 90, and so on.
The first common multiple of 75 and 15 is 75, so the next time when Bus A and Bus B leave the station at the same time will be 75 minutes after their last common departure time, which was 6:00 a.m.
Therefore, the next time when Bus A and Bus B will leave the bus station at the same time is 7:15 a.m., which is option B.