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Calculate the pH of a 7.75x10^-12 M Hydrobromic acid solution. Ph=______(round to 4sig figs). The solution is?________(acidic/basic)

User Jim Burnell
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1 Answer

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18 votes

Answer:

pH = 6.999

The solution is acidic.

Step-by-step explanation:

HBr is a strong acid, a very strong one.

In water, this acid is totally dissociated.

HBr + H₂O → H₃O⁺ + Br⁻

We can think pH, as - log 7.75×10⁻¹² but this is 11.1

acid pH can't never be higher than 7.

We apply the charge balance:

[H⁺] = [Br⁻] + [OH⁻]

All the protons come from the bromide and the OH⁻ that come from water.

We can also think [OH⁻] = Kw / [H⁺] so:

[H⁺] = [Br⁻] + Kw / [H⁺]

Now, our unknown is [H⁺]

[H⁺] = 7.75×10⁻¹² + 1×10⁻¹⁴ / [H⁺]

[H⁺] = (7.75×10⁻¹² [H⁺] + 1×10⁻¹⁴) / [H⁺]

This is quadratic equation: [H⁺]² - 7.75×10⁻¹² [H⁺] - 1×10⁻¹⁴

a = 1 ; b = - 7.75×10⁻¹² ; c = -1×10⁻¹⁴

(-b +- √(b² - 4ac) / (2a)

[H⁺] = 1.000038751×10⁻⁷

- log [H⁺] = pH → 6.999

A very strong acid as HBr, in this case, it is so diluted that its pH is almost neutral.

User Redge
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