Final answer:
The missing proof step states that angles 1 and 4, and angles 3 and 5 are congruent due to the Alternate Interior Angles Theorem because DE is parallel to AC with AB as a transversal.
Step-by-step explanation:
The missing step in the proof that the sum of the interior angles of ∆ABC is 180° is the justification that angles ∠1 and ∠4, and angles ∠3 and ∠5 are congruent. This is true because line DE is drawn parallel to AC, making angles 1 and 4, and angles 3 and 5 pairs of alternate interior angles, which are congruent when the lines are cut by a transversal, in this case, AB. Therefore, the correct answer is: Statement: ∠1 ≅ ∠4, and ∠3 ≅ ∠5. Reason: Alternate Interior Angles Theorem.