435,970 views
16 votes
16 votes
Predict whether the entropy change for this process is positive or negative and explain your answer. Then, predict whether the free energy change for the process is positive or negative and explain your answer.

User ThommyB
by
3.0k points

2 Answers

23 votes
23 votes

Answer:

Consider the spontaneous dissolution of NaCl in water: NaCl(s) → Na+(aq) + Cl −(aq)

Predict whether the entropy change for this process is positive or negative and explain your answer. Then, predict whether the free energy change for the process is positive or negative and explain your answer.

The given question is incomplete. The complete question is:

Consider the spontaneous dissolution of NaCl in water: NaCl(s) → Na(aq) Cl −(aq) Predict whether the entropy change for this process is positive or negative and explain your answer. Then, predict whether the free energy change for the process is positive or negative and explain your answer.

Answer: The entropy change is positive. The free energy change for the process is negative and reaction is spontaneous.

Step-by-step explanation:

Entropy is defined as the degree of randomness of a system. For a system in which randomness increses , the enetropy is said to increase and is positive.

As in the given reaction : , the solid is dissociating to give ions , randomness increases and thus entropy is positive.

Also the dissociation of a molecule requires energy , thus the enthalpy is also positive as heat is absorbed by the system.

when Temperature is high.

Which of these ideas did you include in your answer?

✔️ When a crystalline solid dissolves, it

becomes more disordered.

✔️ When disorder increases, ΔG is positive.

✔️ This process probably has a positive ΔS .

✔️ The process is spontaneous.

✔️ Spontaneous processes have ΔG < 0; the

process has a negative ΔG .

Have a Nice Day .

User Maryuri
by
3.1k points
21 votes
21 votes

The given question is incomplete. The complete question is:

Consider the spontaneous dissolution of NaCl in water: NaCl(s) → Na+(aq) + Cl −(aq) Predict whether the entropy change for this process is positive or negative and explain your answer. Then, predict whether the free energy change for the process is positive or negative and explain your answer.

Answer: The entropy change is positive. The free energy change for the process is negative and reaction is spontaneous.

Step-by-step explanation:

Entropy is defined as the degree of randomness of a system. For a system in which randomness increses , the enetropy is said to increase and
\Delta S is positive.

As in the given reaction :
NaCl(s)\rightarrow Na^+(aq)+Cl^-(aq) , the solid is dissociating to give ions , randomness increases and thus entropy is positive.

Also the dissociation of a molecule requires energy , thus the enthalpy
\Delta H is also positive as heat is absorbed by the system.


\Delta G=\Delta H-T\Delta S


\Delta G=(+ve)-T(+ve)


\Delta G=-ve when Temperature is high.

User Spartikus
by
3.0k points