Let's start in the first information:
This can be verified, because, AC, AB, AD and AE are all congruent, because they are the radius of A and, since BC and DE are congruent, triangles ABC and ADE are also congruent.
Thus, the angles mBAC and mDAE are congruent. The measure of thesee angles are the same as the arcs BC and DE, so we verified this alternative.
In the explanation above, we also verified the second alternative:
And we verified the third alternative:
We are left with the last alternative:
This can't be verified. One way of seeing that is that we can rotate triangle ABC around the circle without changing any of the given information, however this changes mCAD.
So the only statement that cannot be verified from the given information is the last one: