In this question, we have a situation in which we have to use the Calorimetry formula, which is how much heat was released or absorbed (in Joules), after we had a change in temperature of a compound. The formula for this Calorimetry question is:
Q = mcΔT
Where:
Q = is energy as Heat
m = mass in grams, 77.8 grams
c = is the specific heat capacity, 4.184 J/g°C this is for water
ΔT = the change in temperature, calculated as Final Temperature - Initial T
73.8 - 9.3 = 64.5°C
It is important to know that the heat released by the cracker is the same heat absorbed by water but with an opposite mathematical sign, so we have to find out the heat absorbed by water:
Q = 77.8 * 4.184 * 64.5
Q = 20995.7 J is the heat absorbed by water
Therefore the heat released by the cracker is - 20,995.7 J