To find the percertage of families have no children you need to find the total numer of families:
As the total of families is 70.24 millions you consider this data as the 100% of the families.
Then, you calculate the percentage of families have no children as follow:
Families have no children: 35.54million
Total number of families: 70.24 million
Then, the percentage of families have no children is approximately 50.6%