The capacitance C of a parallel-plate capacitor whose plates have an area A and are separated by a distance d is:

Where ε₀ is the vacuum permitivity:

Notice that the capacitance of the parallel-plate capacitor is given, as well as the area of its plates. Then, isolate d from the equation:

Replace A=100mm^2, C=100pF and the value of vacuum permitivity to find the separation between the plates:

Therefore, the correct choice is: 8.85x10^-6m.