The easiest way to solve this problem is to substract 2π from the angle until we get an angle that is less than 2π.

13/3π is not less than 2π, so we have to substract 2π once more:

7/3π is still not less than 2π, substract 2π once more:

1/3π is less than 2π. It means that the positive angle less than 2π that is coterminal with 19/3π is 1/3π.