For the third electron, the electronic configuration is,
![1S^22S^1](https://img.qammunity.org/2023/formulas/physics/college/tynuhodsbr0wknior58254yg4coyc35unx.png)
which shows that,
1. The value of the principle quantum number is,
![n=2](https://img.qammunity.org/2023/formulas/mathematics/college/rkxdas27k0lrnbryyncowymfjali824vcw.png)
2. The value of the angular quantum number is,
![l=0](https://img.qammunity.org/2023/formulas/physics/college/zsyo16kpolbc5kszb5z9mapgqy8t9ah6zx.png)
3. The value of magnetic angular quantum number is,
![m_l=0](https://img.qammunity.org/2023/formulas/physics/college/5x3f9z6zk7663r389cxe2db4le3vff4f0n.png)
4. The value of magnetic spin quantum number is,
![m_s=+(1)/(2)\text{ or -}(1)/(2)](https://img.qammunity.org/2023/formulas/physics/college/3onu61w057te16ryr8nsyatf2m9t8saeb2.png)
Thus, above four points represent the four quantum numbers of the third electron of multi-electron atom.