Let a pound of costa rican coffee be x
Let a pound of organic free coffee be y
x + y = 90
(8x/90) + (13y/90) = 8.22

Therefore we have two equations, which can be solve simultaneously
x + y = 90 ---------1
8x + 13y = 739.8 -------2
make x subject in equation 1
x = 90 -y
substitute x = 90 - y in equation 2
8 ( 90 -y ) + 13y = 739.8
720 - 8y + 13y = 739.8
5y = 739.8 -720
5y = 19.8
divide through by 5
y = 19.8/5 = 3.95
Substitute y =3.95 in x= 90 - y
x = 90 - 3.95 = 86.04
Thus, 3.95 pounds of organic free coffee ne mixed with 86.04 pounds of costa rican coffee