The biggest sum of the two numbers is the only one that can be computed:

There is not much that can be done with the sum since the order does not matter for the result.
Something similar happens with the product. The greatest is:

Since the alternative option for the product between those two numbers gives the same result:

The difference does give us choices. There are two differences that can be computed with that pair of numbers:

From the two results above, the greatest is 3.25.
The quotient also gives us choices:

The greatest quotient is obtained when the largest number is divided by the smallest: 2.18.
Finally:
Greatest sum: 8.75
Greatest difference: 3.25
Greatest product: 16.5
Greatest quotient: 2.18