We are asked to determine the angle of refraction of sunlight when passing through a raindrop. To do that we will use Snell's law:

Where:

The index of refraction of air is 1 and the index of refraction of water is 1.333. Now, we substitute the values:

Now, we divide both sides by 1.333:

Solving the operations we get:

Now, we take the inverse function of sine, and we get:

Now, we solve the operation:

Therefore, the angle of refraction is 16.68°.
A diagram of the situation is the following: