In this example, the scientist made sure to store the bolied water in the flask, but it was not enough for the mountaineer to find it in conditions that the scientist left it. This was because a long time passed and the hot water began to lose heat by conduction through the flask.
Conduction is a way of heat transfer that is caused by direct contact between molecules (in this case, the molecules of the hot water, and the molcules of the walls of the flask), due to the differemce in temperature (hot indside the flask, and cold outside the flask).