ANSWER
The mass of H2O that reacted is 65.88 grams
Step-by-step explanation
Given that;
The volume of oxygen atom at STP is 40.9L
Follow the steps below to find the mass of water reacted
Step 1; Write the balanced equation of the reaction
![\text{ 2H}_2O_((g))\text{ }\rightarrow\text{ 2H}_(2(g))\text{ + O}_(2(g))](https://img.qammunity.org/2023/formulas/chemistry/college/zliznwfnihf9n1gevl244w3iyh5tx6twyh.png)
Step 2; Find the number of moles of oxygen atom
Recall, that 1 moles of a gas at STP is equivalent to 22.4 L/mol
Let x represents the number of moles of oxygen
![\begin{gathered} \text{ 1 mole O}_2\text{ }\rightarrow\text{ 22.4l/mol} \\ \text{ x mole O}_2\text{ }\rightarrow\text{ 40.9 L} \\ \text{ Cross multiply} \\ \text{ 1 mole O}_2\text{ }*\text{ 40.9L = x mole O}_2*\text{ 22.4 L/mol} \\ \text{ Isolate x mole O}_2 \\ \text{ x mole O}_2\text{ = }\frac{1\text{ mole O}_2*40.9\cancel{L}}{22.4\text{ }\frac{\cancel{L}}{mol}} \\ \\ \text{ x mole O}_2\text{ = }\frac{1\text{ }*\text{ 40.9}}{22.4} \\ \text{ x mole O}_2\text{ = }(40.9)/(22.4) \\ \text{ x mole O}_2\text{ = 1.83 moles} \end{gathered}](https://img.qammunity.org/2023/formulas/chemistry/college/n0eqcrkc2sedj0xdldf6mqxn34wphyev83.png)
The moles of O2 is 1.83 moles
Step 3; Find the number of moles of H2O using a stoichiometry ratio
Let x represents the number of moles of H2O
In the given reaction, 2 moles of water give 1 mole of O2
![\begin{gathered} \text{ 1 mole O}_2\text{ }\rightarrow\text{ 2 moles H}_2O \\ \text{ 1.83 moles O}_2\text{ }\rightarrow\text{ x moles H}_2O \\ \text{ cross multiply} \\ \text{ 1 mole O}_2\text{ }*\text{ x moles H}_2O\text{ = 2 moles H}_2O\text{ }*\text{ 1.83 moles O}_2 \\ \text{ Isolate x moles H}_2O\text{ } \\ \text{ x moles H}_2O\text{ = }\frac{\text{ 2 moles H}_2O*1.83moles\cancel{O_2}}{1mole\cancel{O_2}} \\ \\ \text{ x moles H}_2O\text{ = 2 }*\text{ 1.83} \\ \text{ x moles H}_2O\text{ = 3.66 moles} \end{gathered}](https://img.qammunity.org/2023/formulas/chemistry/college/ce5yf2cet2wxn52n5m6qqazpizkct6nlww.png)
The number of moles of H2O is 3.66 moles
Step 4; Find the mass of H2O using the formula below
![\begin{gathered} \text{ mole = }\frac{\text{ mass}}{\text{ molar mass}} \\ \text{ cross multiply} \\ \text{ mass = mole }*\text{ molar mass} \end{gathered}](https://img.qammunity.org/2023/formulas/chemistry/college/yfdw03dlfxd00xfkmpn0lchpakfjg43h0d.png)
Recall, that the molar mass of water is 18.0 g/mol
![\begin{gathered} \text{ mass = 3.66 }*\text{ 18} \\ \text{ mass = 65.88 grams} \end{gathered}](https://img.qammunity.org/2023/formulas/chemistry/college/lsqgqthza2vmrafmmpx73jyjiysu7nr0ne.png)
Therefore, the mass of H2O that reacted is 65.88 grams