From the given diagram, we get that the surface area of the walls of the rectangular room (without the 5m² for the door and windows) is:

Simplifying the above result we get:

Since one liter of paint covers 9.5m², then Shelby needs:

liters of paint.
Therefore, the least amount of paint that Shelby must buy to paint the room is 6 liters.
Now, notice that:

Then Shelby can buy a can of 4L of paint and 2 cans of 1L of paint. Using the given table we get that the paint cost:

dollars.
Answer:
(a) 6 liters.
(b) $40.93.