Let's see that the STP represents the conditions for the temperature of 0°C (273 K) and for the pressure of 1 atm.
We have this initial data and a volume of 3.20 x 10 ^(2) mL. To solve this problem, we need to use the ideal gas formula:
![(P_1V_1)/(T_1)=(P_2V_2)/(T_2),](https://img.qammunity.org/2023/formulas/chemistry/college/2mvl0pmwvv07a7h44tbptz2c5jkxmoeaym.png)
where T is temperature, P is pressure, and V volume. Subindex 1 is the initial data and subindex 2 is the final data.
We want to find the final volume, so clearing for V2 in the formula, we're going to obtain:
![V_2=(P_1V_1T_2)/(T_1P_2)\text{.}](https://img.qammunity.org/2023/formulas/chemistry/high-school/xr7d550rvz5ak32twg1ig4zyfdvqhi4na6.png)
And the final step is replacing the data that we have, where the final data is 425.0 K and 3.50 atm (remember that the volume must be in liters, 1 liter is 1000 mL, so 3.20 x 10^2 mL is 0.32 L):
![\begin{gathered} V_2=\frac{1\text{ atm }\cdot\text{ 0}.32\text{ L }\cdot425.0K}{273\text{ K }\cdot\text{ 3.50 atm}}, \\ V_2=0.14\text{ L.} \end{gathered}](https://img.qammunity.org/2023/formulas/chemistry/high-school/8ls44n9tszdt7fdij5817fwnoqvmkdp3yl.png)
The answer is that the new volume of the sample of helium would be 0.14 L.