To solve this problem we need to know first how many mols of water we have. To do that we use the Ideal gas law with the that provided:
![\begin{gathered} PV=nRT \\ n=(PV)/(RT)=(1atm\cdot50L)/(0.082(amt\cdot L)/(K\cdot mol)\cdot523.15K)=1.166mol \end{gathered}](https://img.qammunity.org/2023/formulas/chemistry/college/e76er7b442z5v8jaqwce882crpq1dzbjkf.png)
according to the chemical equation we know that 3 mols of water react with 2 mols of iron, we can use this information as a conversion factor to know how many mols of iron react with 1.166 mols of water:
![1.166mols\text{ of water}\cdot\frac{2mols\text{ of Fe}}{3\text{ mols of water}}=0.777mols\text{ of Fe}](https://img.qammunity.org/2023/formulas/chemistry/college/cbpy6zg2wy2l7l126pxg30mgaeaqi1ik7t.png)
and last we have to convert those mols into mass. To do that we use the molar mass of Iron 55.845g/mol:
![m_(Fe)=n_(Fe)\cdot Mm_(Fe)=0.777mols\cdot55.845g/mol=43.939\text{ g}](https://img.qammunity.org/2023/formulas/chemistry/college/2l79u3bviqa4htpils3sk7b4q57y1wtcza.png)
the mas of Iron is 43.939g