(a)
As the decay of pion into two photons takes place in the train. The two photons have equal (same magnitude) and opposite (direction) momentum in the train.
As one is heading to the front while the other is heading back; according to the person in the train, the events seems normal (inertial frame).
Thus, both photons are traveling at the same speed and reach at the same time.
Therefore, option (C); they both arrive at the same time is the correct choice.
(b)
According to the person on the Lab frame (rest), the velocity (relative velocity) of the photons changes.
Thus, the time taken by the photons to reach is different.
As the photon traveling towards the right (front of the car) seems to travel faster than the photon which is moving towards the back of the car.
Therefore, option (B); no, is the correct choice.