Step 1
Molarity is defined as follows:

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Step 2
Information provided:
A solution made up of KCl + Water (H2O),
0.38 g KCl
625 mL H2O x (1 L/1000 mL) = 0.625 L
(Note: we need the volume of the solution in L, but we don't have the density of water or the density of solution so we assume the volume of water equal to the volume of water used)
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Information needed:
The molar mass of KCl = 39.10 g/mol + 35.453 g/mol = 74.553 g/mol
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Step 3
The number of moles of KCl, n
n = mass of KCL/the molar mass of KCl
n = 0.38 g/75.553 g/moles = 5.03x10^-3 moles
Molarity,
Molarity = 5.03x10^-3 moles/0.625 L = 8.048x10^-3 M
Answer: 8.048x10^-3