The rock travels a horizontal distance x after time t of
x = (12.2 m/s) cos(63°) t
If it hits the ground 25 m away from where it was thrown, then for some time t we have
25 m = (12.2 m/s) cos(63°) t
Solve for t :
t = (25 m) / ((12.2 m/s) cos(63°))
t ≈ 4.5 s