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If the density of a gas is 1.2 g/L at 745 torr and 20 degree celsius, what is its molecular mass?R = 0.0821 L.atm/K.mol

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The question requires us to calculate the molecular mass of a gas, given its density (1.2 g/L) and conditions of pressure (745 torr) and temperature (20°C).

Density is defined as the mass of a compound over its volume. From this definition, we can calculate the molecular mass of the gas knowing the density, as given by the question, and the volume of 1 mol of the gas.


\text{density = }\frac{mass}{\text{volume}}\to\text{mass = volume }*\text{ density}

We can calculate the volume of a gas considering the equation of Ideal Gases:


P* V=n* R* T

where P is the pressure of the gas, V is its volume, n is the number of moles, R is the constant of gases and T is the temperature.

Note that the constant of gases R was given in units of L.atm/K.mol, while the pressure and temperature were given in Torr and °C, respectively. Thus we need to convert these values to the appropriate units.

Knowing that 1 Torr corresponds to 0.00131579 atm:

1 Torr --------------------- 0.00131579 atm

745 Torr ---------------- x

Solving for x, we have that 745 Torr corresponds to 0.980 atm.

To convert the temperature from Celsius degrees to Kelvin, we must add 273.15:

T = 20 + 273.15 K = 293.15 K

Therefore, the pressure and temperature we'll use in our calculation are 0.980 atm and 293.15 K. Also, since we are calculating the molecular mass, we'll consider 1 mol of gas.

Rearranging the equation of ideal gases to calculate the volume and applying the values to the equation, we'll have:


\begin{gathered} P* V=n* R* T\to V=(n* R* T)/(P) \\ V=\frac{(1mol)*(0.0821L.atm/K.mol)*(293.15K)}{(0.980\text{atm)}}=24.6L \end{gathered}

Therefore, the volume of 1 mol of the gas under the conditions given is 24.6L.

Next, we'll use this value to calculate the molecular mass using the density given by the question:


\begin{gathered} \text{mass = volume }*\text{ density} \\ \text{mass = 24.6L}*1.2g/L \\ \text{mass = }29.5g/\text{mol} \end{gathered}

Therefore, the gas given by the question presents 29.5g per mol.

User Bernd Ruecker
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