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How to balance using half reaction method? Just the 3rd question.

How to balance using half reaction method? Just the 3rd question.-example-1
User Thea
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Answer:


3CH_3OH+2Cr_2O_7^(2-)+16H^+\operatorname{\rightarrow}3HCO_2H+4Cr^(3+)+11H_2O

Expanations:

Given the unbalanced chemical reaction


Cr_2O_7^(2-)+CH_3OH→HCO_2H+Cr^(3+)

Separate into half reactions


\begin{gathered} Cr_2O_7^(2-)\rightarrow Cr^(3+)(Reduction) \\ CH_3OH\rightarrow HCO_2H(Oxidation) \end{gathered}

Balance all other atoms except hydrogen and oxygen to have:


\begin{gathered} CH_3OH\rightarrow HCO_2H \\ Cr_2O_7^(2-)\rightarrow2Cr^(3+) \end{gathered}

Balance the oxygen atoms by adding water


\begin{gathered} CH_3OH+H_2O\rightarrow HCO_2H \\ Cr_2O_7^(2-)\operatorname{\rightarrow}2Cr^(3+)+7H_2O \end{gathered}

Balance the hydrogen atoms by adding hydrogen ion


\begin{gathered} CH_3OH+H_2O\operatorname{\rightarrow}HCO_2H+4H^+ \\ Cr_2O_7^(2-)+14H^+\operatorname{\rightarrow}2Cr^(3+)+7H_2O \end{gathered}

Balance the charges


\begin{gathered} CH_3OH+H_2O\operatorname{\rightarrow}HCO_2H+4H^++4e^-\text{ * 3} \\ Cr_2O_7^(2-)+14H^++6e^-\operatorname{\rightarrow}2Cr^(3+)+7H_2O\text{ * 2} \\ _(------------------------------------) \\ 3CH_3OH+3H_2O\operatorname{\rightarrow}3HCO_2H+12H^++12e^- \\ 2Cr_2O_7^(2-)+28H^++12e^-\operatorname{\rightarrow}4Cr^(3+)+14H_2O \end{gathered}

Cancel the charges and add the resulting equation to have:


3CH_3OH+2Cr_2O_7^(2-)+16H^+\rightarrow3HCO_2H+4Cr^(3+)+11H_2O

User Ichigo
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