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I have to figure out the molar enthalpy kj/mol of the combustion of methanol from the data

I have to figure out the molar enthalpy kj/mol of the combustion of methanol from-example-1
User Logworthy
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1 Answer

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1. Calculate heat change,q, using equation: q = mass* C * ∆T

• given that volume = 230ml ,therefore mass of water = 230g

,

• ∆T = Tfinal-Tinitial =30.5-22.9 = 7.6°C

,

• Specific heat capacity of water , C= 4.184J/°C*g

• Therefore , q = mass* C * ∆T

= 230 * 4.184 * 7.6

=7313.6 J /1000

q= 7.314KJ

2. Calculate Molar enthalpy using ∆H = q/n

• given : mass of methanol burned = Mass F-Mass initial

=(2.51-1.65) = 0.86 g

• So ,moles of methanol , n = mass methanol/Mol. mass methanol

= 0.86g/32.04g/mol

=0.027 moles

• Finally , ∆H = q/n

= 7.314KJ / 0.027mol

=270.85KJ/mol

• However, this is an exorthemic reaction, heat is lost through combustion, our molar enthalpy should be negative.

This means that ∆H= -270.85KJ/mol

User Lordhong
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