Final answer:
To balance the given redox reaction in a basic solution, follow these steps: balance the atoms and charges in each half-reaction, multiply each half-reaction by a factor that will make the total charge on each side of the equation equal, and add the two balanced half-reactions to obtain the final balanced equation. If the reaction takes place in a basic solution, add OH- ions to both sides of the equation to neutralize H+ ions.
Step-by-step explanation:
To balance the given redox reaction in a basic solution, follow these steps:
Balance the atoms and charges in each half-reaction.
Multiply each half-reaction by a factor that will make the total charge on each side of the equation equal.
Add the two balanced half-reactions to obtain the final balanced equation.
If the reaction takes place in a basic solution, add OH- ions to both sides of the equation to neutralize H+ ions.
For the given reaction:
MnO4–(aq) + Cl–(aq) → MnO2(s) + Cl2(g)
The balanced half-reactions are:
Oxidation: MnO4– + H2O → MnO2 + OH-
Reduction: 2Cl– → Cl2 + 2e-
Adding the half-reactions and simplifying gives the final balanced equation:
MnO4– + 2Cl– + H2O → MnO2 + Cl2 + OH-