158k views
3 votes
I need help calculating the Kc for both of these reactions.

I need help calculating the Kc for both of these reactions.-example-1
User Turiyag
by
4.7k points

1 Answer

5 votes

Given the equation :

CH3OH +Cl2 →← 2 CH3CL + 2OH ^-1

at equilibrium concentration, we have:

(1.5 -2x )/ 5L + (1.0 -x )/5L =2x /5L + 2x /5L

→ (1.5-2x+ 1 -x )/ 5L = 4x /5L

→(0.5 -3x)/5L = 4x/5L (5L in the Left hand side cancels 5L inthe right hand side)

→ 0.5 = 4x +3x

0.5 = 7x

x = 0.5/7

x = 0.071

( Extra note : Now lets test and see if this balances ):

LHS : (1.5 -2x )/ 5L + (1.0 -x )/5L = 0.5 -3x)/5L

= 0.5 - 3(0.071)/5

= 0.287 /5 = 0.05

RHS :4(x) /5 = 4(0.071) /5

= 0.28/5 = 0.05

at equlibrium , LHS = RHS therefore our x value is 0.07

User Dinara
by
4.8k points