Answer:
28.22L of HF are needed.
Step-by-step explanation:
1st) It is necessary to convert the 14.2L H2 to moles, using the relation for gases that 22.4L is equal to the volume of 1 mole:
![\begin{gathered} 22.4L-1mol \\ 14.2L-x=(14.2L*1mol)/(22.4L) \\ x=0.63moles \end{gathered}](https://img.qammunity.org/2023/formulas/chemistry/college/h613lq342qcllg26phalmqv69zwk2000xk.png)
2nd) Now, with the stoichiometry of the balanced reaction (we know that 1 mole of H2 is formed from 2 moles of HF), and the 0.63 moles of H2, we can calculate the moles of HF needed:
![\begin{gathered} 1molH_2-2molHF \\ 0.63molH_2-x=(0.63molH_2*2molHF)/(1molH_2) \\ x=1.26molHF \end{gathered}](https://img.qammunity.org/2023/formulas/chemistry/college/r0ff5vgvdqzwxi3t8g4k9o703j0buw55ow.png)
Now we know that 1.26 moles of HF can produce 14.2L (0.63moles) of H2 gas.
3rd) Finally, we have to convert the 1.26 moles of HF to liters:
![\begin{gathered} 1mole-22.4L \\ 1.26moles-x=(1.26moles*22.4L)/(1mole) \\ x=28.22L \end{gathered}](https://img.qammunity.org/2023/formulas/chemistry/college/d4rnc7gp9s4kvbykdkli2d87dm7sklpm7q.png)
So, 28.22L of HF are needed.